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Beilstein J. Org. Chem. 2014, 10, 767–773, doi:10.3762/bjoc.10.72
Graphical Abstract
Figure 1: Published 70 eV EI mass spectra of the naturally occurring compounds A and B [12].
Figure 2: Synthesis of tetramethyltrideca-2,4-dienes 8, 14 and 15. Conditions: a: LiAlH4, Et2O, −30 °C to rt,...
Figure 3: 70 eV EIMS of synthetic tetramethyltrideca-2,4-dienes 8, 14 and 15. These spectra were run under th...
Figure 4: Synthesis of (2E,4EZ)-syn,syn-4,6,8,10-tetramethyltrideca-2,4-diene (22), as well as (2E,4E)- and (2...
Beilstein J. Org. Chem. 2012, 8, 1256–1264, doi:10.3762/bjoc.8.141
Figure 1: Structures of cis- and trans-fused iridoid lactones.
Figure 2: 70 eV EI-mass spectrum of compounds Y and Z of Alloxysta victrix.
Figure 3: Chemical structures of all eight stereoisomers of trans-fused iridomyrmecins and their gas chromato...
Figure 4: Strategy for the stereoselective synthesis of trans-fused iridomyrmecins A–D from (R)-limonene.
Scheme 1: Synthesis of the trans-fused iridomyrmecins A and B. Reaction conditions and yields: a) ammonium fo...
Figure 5: Configurations of the trans-fused iridomyrmecins A and B’.
Scheme 2: Synthesis of the trans-fused iridomyrmecins C and D. Reaction conditions and yields: a) Crabtree's ...
Figure 6: Configurations of the trans-fused iridomyrmecins C and D’.
Figure 7: Volatile terpenoids in the cephalic secretion of Alloxysta victrix. For the identification of compo...
Figure 8: Structures of iridoids from insects and plants. Absolute configurations of 19 and 20 are "educated ...
Figure 9: Biosynthetic ways to iridoids from geraniol.